Rovibrational spectra of diatomic molecules in strong electric fields
نویسندگان
چکیده
منابع مشابه
Rovibrational dynamics of LiCs dimers in strong electric fields
We investigate the effects of a strong electric field on the rovibrational dynamics of LiCs in its R electronic ground state. Using a hybrid computational technique combining discretisation and basis set methods, the rovibrational Schrödinger equation is solved. Results for energy levels and various expectation values are presented. The validity of the previous developed effective and adiabatic...
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Clearly N is perpendicular to R, so the projection of J onto R is the same as the projection LR with eigenvalue ¤1 h of L. (We now reserve z for a direction ̄xed in space, and use the subscript R for a component along R). Because total angular moment of an isolated molecule is constant, eigenfunctions of H when L is non-zero will have the quantum numbers J , MJ , ¤, s (to describe the electronic...
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Fully numerical mesh solutions of 2D and 3D quantum equations of Schrödinger and Hartree-Fock type allow us to work with wavefunctions which possess a very flexible geometry. This flexibility is especially important for calculations of atoms and molecules in strong external fields where neither the external field nor the internal interactions can be considered as a perturbation. In the framewor...
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Fully numerical mesh solutions of 2D quantum equations of Schrödinger and Hartree-Fock type allow us to work with wavefunctions which possess a very flexible geometry. This flexibility is especially important for calculations of atoms and molecules in strong external fields where neither the external field nor the internal interactions can be considered as a perturbation. The applications of th...
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R. González-Férez* and P. Schmelcher Departamento de Física Moderna and Instituto “Carlos I” de Física Teórica y Computacional, Universidad de Granada, E-18071 Granada, Spain Theoretische Chemie, Physikalisch-Chemisches Institut, Im Neuenheimer Feld 229, D-69120 Heidelberg, Germany Physikalisches Institut, Universität Heidelberg, Philosophenweg 12, D-69120 Heidelberg, Germany sReceived 26 Novem...
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ژورنال
عنوان ژورنال: Journal of Physics: Conference Series
سال: 2005
ISSN: 1742-6588,1742-6596
DOI: 10.1088/1742-6596/4/1/041